1202.4284 (M. Borówko et al.)

Changes in the structure of tethered chain molecules as predicted by
density functional approach    [PDF]

M. Borówko, A. Patrykiejew, O. Pizio, S. Sokołowski

We use a version of the density functional theory to study the changes in the
height of the tethered layer of chains built of jointed spherical segments with
the change of the length and surface density of chains. For the model in which
the interactions between segments and solvent molecules are the same as between
solvent molecules we have discovered two effects that have not been observed in
previous studies. Under certain conditions and for low surface concentrations
of the chains, the height of the pinned layer may attain a minimum. Moreover,
for some systems we observe that when the temperature increases, the height of
the layer of chains may decrease.

View original: http://arxiv.org/abs/1202.4284