Thursday, May 10, 2012

1205.1983 (Marcia M. Szortyka et al.)

Connection Between Minimum of Solubility and Temperature of Maximum
Density in an Associating Lattice Gas Model
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Marcia M. Szortyka, Maurício Girardi, Vera B. Henriques, Marcia C. Barbosa
In this paper we investigate the solubility of a hard - sphere gas in a solvent modeled as an associating lattice gas (ALG). The solution phase diagram for solute at 5% is compared with the phase diagram of the original solute free model. Model properties are investigated thr ough Monte Carlo simulations and a cluster approximation. The model solubility is computed via simulations and shown to exhibit a minimum as a function of temperature. The line of minimum solubility (TmS) coincides with the line of maximum density (TMD) for different solvent chemical potentials.
View original: http://arxiv.org/abs/1205.1983

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