Thursday, January 24, 2013

1301.5444 (J. Pekalski et al.)

Periodic ordering of clusters in a one-dimensional lattice model    [PDF]

J. Pekalski, A. Ciach, N. G. Almarza
A generic lattice model for systems containing particles interacting with short-range attraction long-range repulsion (SALR) potential that can be solved exactly in one dimension is introduced. We assume attraction J_1 between the first neighbors and repulsion J_2 between the third neighbors. The ground state of the model shows existence of two homogeneous phases (gas and liquid) for J_2/J_1<1/3. In addition to the homogeneous phases, the third phase with periodically distributed clusters appears for J_2/J_1>1/3. Phase diagrams obtained in the self-consistent mean-field approximation for a range of values of J_2/J_1 show very rich behavior, including reentrant melting, and coexistence of two periodic phases (one with strong and the other one with weak order) terminated at a critical point. We present exact solutions for the equation of state as well as for the correlation function for characteristic values of J_2/J_1. Based on the exact results, for J_2/J_1>1/3 we predict pseudo-phase transitions to the ordered cluster phase indicated by a rapid change of density for a very narrow range of pressure, and by a very large correlation length for thermodynamic states where the periodic phase is stable in mean field. For 1/9View original: http://arxiv.org/abs/1301.5444

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