1303.0562 (I. A. Ar'ev et al.)

Effects of partial charge-transfer solute -- solvent interactions in
absorption spectra of aromatic hydrocarbons in aqueous and alcoholic
solutions    [PDF]

I. A. Ar'ev, N. I. Lebovka, E. A. Solovieva

A method for study of charge-transfer interactions between solute molecules and solvent based on the comparison of the ratios of spectral shifts of different electronic transitions in solute molecules in chemically inert solvent is proposed. The method is applicable to molecules that do not change their dipole moment on excitation. As an example, a presence of charge transfer interactions in higher electronic states of aromatic hydrocarbons (benzene, phenanthrene, and naphthalene) dissolved in water and alcohols was demonstrated.

View original: http://arxiv.org/abs/1303.0562